ChemInform Abstract: Synthesis of (24R,28R)‐ and (24S,28S)‐24,28‐Methylene‐5‐stigmasten‐3β‐ol and Biosynthetic Implications of Cyclopropyl Cleavage to 24‐Substituted Cholesterols

Journal article

J.‐L. Giner, M. P. Zimmerman and C. Djerassi

ChemInform, Vol.20(22), pp.no-no

05/30/1989

Abstract

cleavage reactions, decomposition reactions, pyrolysis

rearrangements

steroids

Treatment of methylenestigmastenol (I) with trifluoroacetic acid results in opening of the cyclopropane ring, producing the olefins (II) ‐(IV).

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Title: ChemInform Abstract: Synthesis of (24R,28R)‐ and (24S,28S)‐24,28‐Methylene‐5‐stigmasten‐3β‐ol and Biosynthetic Implications of Cyclopropyl Cleavage to 24‐Substituted Cholesterols
Creators - without role: J.‐L. Giner
M. P. Zimmerman
C. Djerassi
Publication Details: ChemInform, Vol.20(22), pp.no-no
Publisher: WILEY‐VCH Verlag GmbH
Number of pages: 1
Identifiers: 99893660604826
Academic Unit: Department of Chemistry
Language: English
Resource Type: Journal article